Material Safety Data Sheet Duffy Yellow Label Thinner (Sodium Silicate):
Date Prepared: 03/01/2008 MSDS No: M35887
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name:
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Sodium Silicate Liquid Siliceous (all grades)
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Product Description:
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Thinner for Stop-Off Paints
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Manufacturer:
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Occidental Chemical Corporation, Occidental tower
5005 LBJ Freeway, PO Box 809050
Dallas, TX 75380
(972) 404-3800
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24 Hour Emergency Phone:
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1-800-733-3665 or (972) 404-3228
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To request an MSDS
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1-800-699-4970
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Customer Service
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1-800-752-5151
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Product Use:
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Adhesives: pulp and paper: deinking: detergents: gels: catalysts: soil stabilization: textiles.
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Chemical Name:
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Sodium Silicate Liquid
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Chemical Formula:
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Na20.xSi02 (x>2.55 by weight)
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Synonyms/Common Names:
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Liquid Sodium Silicate, Water Glass, Sodium Silicate Liquid Siliceous
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COMPOSITION/INFORMATION ON INGREDIENTS
CAS NUMBER: 7732-18-5
NAME: water
EXPOSURE LIMITS
PEEL: Not established
VOL: ND
TLV: Not established
Wt.: 51-65
COMMON NAMES: Listed on (List Legend Below)
00 19 22 23 50 51
1344-09-8 Silicic acid, sodium salt
EXPOSURE LIMITS
PEL: Not established
TLV: Not Established
VOL: ND
Wt.: 35-49
COMMON NAMES: Sodium Silicate Liquid
Listed on (List legend below):
00 19 22 23 50 51
LIST LEGEND
00 TSCA INVENTORY
22 CANADIAN DOMESTIC SUB LIST
50 PHILIPPINES INVENTORY (PICCS)
19 PA REQUIREMENT- 3% OR GREATER
23 NJ REQUIREMENT- 1% OR GREATER
51 EINECS
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HAZARDS IDENTIFICATION
Emergency overview:
Irritating to eyes, skin, respiratory tract and gastrointestinal tract
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Potential health effects:
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ROUTES OF ENTRY:
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Ingestion, Inhalation.
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TARGET ORGANS:
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Eyes, Skin, Respiratory Tract, and Gastrointestinal Tract.
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IRRITANCY:
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Potentially by all routes of exposure.
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SENSITIZING CAPABILITY:
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None known.
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REPRODUCTIVE EFFECTS:
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None known.
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CANCER EFFECTS:
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None known.
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EYES:
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Irritating to eyes, causing pain, redness and tearing.
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SKIN:
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May be irritating.
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INHALATION:
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May cause coughing, sneezing or other symptoms of upper respiratory tract irritation.
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INGESTION:
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May cause irritation of the mouth, throat, esophagus and stomach.
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REPEATED EXPOSURE (CHRONIC):
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No known effects.
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SYNERGISTIC MATERIALS:
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None known.
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MEDICAL CONDITIONS AGGRAVATED BY EZPOSURE:
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None known.
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FIRST AID MEASURES
EYES:
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IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes, forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. IF IRRITATION PERSISTS GET MEDICAL ATTENTION.
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SKIN:
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Wash thoroughly with soap and water. Wash clothing before reuse. IF IRRITATION OCCURS, GET MEDICAL ATTENTION.
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INGESTION:
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NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. (If available, give several glasses of milk.) If vomiting occurs spontaneously, keep airway clear and give more water. GET MEDICAL ATTENTION IMMEDIATELY.
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INHALATION:
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Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops, have trained person administer artificial respiration. GET MEDICAL ATTENTION IMMEDIATELY.
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NOTES TO PHYSICIAN:
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No special procedures. Treat for clinical symptoms.
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FIRE FIGHTING MEASURES
Flashpoint:
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Nonflammable
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METHOD:
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Not applicable
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AUTO IGNITION TEMPERATURE:
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Nonflammable
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FLAMMABLE LIMITS IN AIR, BY % VOLUME:
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UPPER:
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Not applicable
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LOWER:
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Not applicable
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EXTINGUISHING MEDIA:
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Nonflammable/noncombustible. Use agents appropriate for surrounding fire.
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FIRE FIGHTING PROCEDURES:
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Wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus and full protective clothing.
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FIRE AND EXPLOSION HAZARD:
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Non known
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SENSITIVITY TO MECHANICAL IMPACT:
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Not sensitive
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SENSITIVITY TO STATIC DISCHARGE:
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Not sensitive
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ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE:
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Evacuate unnecessary personnel. Follow protective measures provided under personal Protection in Section "EXPOSURE CONTROLS/PERSONAL PROTECTION".
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ENVIRONMENTAL PRECAUTIONS:
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Contain spill with dike to prevent entry into sewers or waterways. Spills or releases should be reported, if required, to the appropriate local, state agencies.
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METHODS FOR CLEANING UP:
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Dry material can be shoveled up, liquid material can be removed with a vacuum truck. Neutralize remaining traces with any dilute inorganic acid (hydrochloric, sulfuric or acetic acid). Flush spill area with water followed by liberal covering of sodium carbonate. All clean-up material should be removed for proper treatment or disposal. Spills on other than pavement (e.g. Dirt or sand) may be handled by removing the affected soil and placing in approved containers.
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HANDLING AND STORAGE
HANDLING:
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Wear personal protective equipment as describes in Exposure Controls/Personal Protection (Section 8) of the MSDS. Do not get in eyes, on skin or clothing. Avoid breathing airborne particulates; wear respiratory protection when exposure is possible. Wash contaminated clothing before reuse. Wash thoroughly with soap and water after handling.
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SPECIAL MIXING AND HANDLING INSTRUCTIONS:
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Do not allow contact with materials as noted in Section 10. Contact with acids will cause gelling and the evolution of heat.
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STORAGE:
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Keep container tightly closed and properly labeled. Do not store in aluminum container or use aluminum fittings or transfer lines, as flammable hydrogen gas can be generated.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
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use adequate local exhaust ventilation where dust, mist or spray may be generated.
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PERSONAL PROTECTION:
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RESPIRATORY:
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Wear a NIOSH/MSHA approved respirator following manufacturer’s recommendations, where airborne contaminants may occur.
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EYE/FACE:
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Wear chemical safety goggles plus full-face shield to protect against contact when appropriate (ANSI Z87.1).
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SKIN:
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Wear protective clothing to minimize skin contact. Wear chemical resistant gloves such as rubber, neoprene or vinyl. Wash contaminated clothing and dry before reuse.
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OTHER:
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Emergency shower and eyewash facility should be in close proximity (ANSI Z358.1).
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PHYSICAL AND CHEMICAL PROPERTIES
PROPERTY:
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40
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42
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47
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49FG
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Weight ratio- Si02: Na20:
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3.22
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3.22
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2.84
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2.58
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Total solids, %:
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38.3
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39.3
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43.1
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44.5
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Specific Gravity @ 20°C (H20=1):
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1.40
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1.41
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1.48
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1.51
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pH:
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11.2
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11.2
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11.6
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11.6
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Density, lb./gal @ 20°C (68°F):
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11.7
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11.8
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12.3
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12.6
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Appearance and Odor: Colorless, turbid liquid, none to slightly soapy odor
Odor Threshold: Not available
Vapor Pressure: Not applicable
Vapor Density (Air=1): Not applicable
Evaporation Rate: Not applicable
% Volatiles by weight: <65%
Boiling Point @ 760 mm Hg: 214-216°F (101-102°C)
Freezing Point: 30°F (1°C)
Solubility in H20, % by wt.: 100%
Octanol/Water Partition Coefficient: Not applicable
Thermal Decomposition Temperature: Not applicable
VOC (g/l by wt.): Not applicable
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STABILITY AND REACTIVITY
CHEMICAL STABILITY:
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Stable
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REACTS WITH:
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Acids & Metals
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HAZARDOUS POLYMERIZATION:
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Will not occur
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HAZARDOUS DECOMPOSITION PRODUCTS:
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None
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COMMENTS:
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Contact with acids will cause gelling and the evolution of heat. Prolonged contact with aluminum may produce flammable hydrogen gas.
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TOXICOLOGICAL INFORMATION
1344-08-8 Silicic acid, sodium salt
ACUTE ORAL LD50: (rat) 2000 to 3000 mg/kg
This product is an alkaline solution.
Exposure to this material may be evaluated as: PEL= 2mg Ceiling as NaOH
TLV= 2mg Ceiling as NaOH
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ECOLOGICAL INFORMATION
1344-09-8 Silicic Acid, sodium slat
AQUATIC ECOTOX DATA
Fish: LC50 (96 hr.) (Mosquitofish) 1,800-2,320 mg/L
Invertebrates: EC50 (100 hr.) (Water flea) 247 mg/L
LC50 (48 hr.) (Water flea) 494 mg/L
LC50 (96 hr.) (Scud) 160 mg/L
LC50 (96 hr) (pond snail) 632 mg/L
LC50 (28 day) (polycheate worm 643-765 ug/L
Plant: EC (7 day) (phytoplankton) 1,500 ug/L
TERRESTRIAL ECOTOX DATA
Wildlife: LD (oral) mouse 1.1 gm/Kg
ENVIRONMENTAL FATE DATA
Biotic: Biodegradation Inorganic, not subject to biodegradation
Abiotic: water solubility 100%
There is limited information on the environmental fate of this material. Laboratory tests indicate that it exhibits low toxicity to aquatic organisms and moderate toxicity to terrestrial animals. This material is inorganic and not subject to biodegradation. This compound is strongly alkaline and may raise the pH if dissolved in surface water. Due caution should be exercised to avoid the release of this material to environment.
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DISPOSAL CONSIDERATIONS
Disposal method:
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Dispose of all waste and contaminated equipment in accordance with all applicable federal, state and local health and environmental regulations.
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TRANSPORT INFORMATION
DOT INFORMATION: Not regulated
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REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, material safety data sheets, training and access to written records. We request that you and it is your legal duty to make all information in the Material Data Safety Sheet available to your employees.
To aid our customers in complying with regulatory requirements, SARA Title III Hazard Categories for this product are indicated below. If the word “YES” appears next to any category, this product may be reportable by you under the requirements of 40.CFR.370. Please consult those regulations for details.
TSCA: All components of this product tat are required to be on the TSCA inventory are listed on the inventory.
SARA/TITLE III HAZARD CATEGORIES:
Immediate (Acute) Health: YES
Reactive Hazard: NO
Delayed (Chronic) Health: NO
Sudden release of Pressure: NO
Fire Hazard: NO
HMIS HAZARD RATINGS:
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
STATE REGULATIONS:
See Section 2. COMPOSITION/INFORMATION ON INGREDIENTS list legend for applicable state regulation.
Consult local laws for applicability
INTERNATIONAL REGULATIONS:
Consult the regulations of the importing country.
CANADA:
WHMIS Hazard Class: NOT CLASSIFIABLE
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OTHER INFORMATION
For additional non emergency health, safety or environmental information telephone (972) 404-2405 or write to:
Occidental Chemical Corporation
Product Stewardship Department
5005 LBJ Freeway
PO Box 809050
Dallas, Texas 75380
MSDS LEGEND
ACGIH = American Conference of Governmental Industrial Hygienists
CAS = Chemical Abstracts Service Registry
CEILING = Ceiling Limit (15 minutes)
CEL = Corporate Exposure Limit
OSHA = Occupational Safety and Health Administration
PEL = Permissible Exposure Limit (OSHA)
STEL = Short Term Exposure Limit (15 minutes)
TDG = Transportation of Dangerous Goods (Canada)
TLV = Threshold Limit Value (ACGIH)
TWA = Time Weighted Average (8 hours)
WHMIS = Worker Hazardous Materials Information System (Canada)
* = See section 3 Hazards Identification – Repeated Exposure (Chronic) Information
IMPORTANT: The information presented herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR FITNESS FOR PURPOSE, OR ANY OTHER KIND, EXPRESS OR IMPLIED, IS MADE REGARDING PERFORMANCE, STABILITY OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of use, handling or storage. Other factors may involve other or additional safety or performance considerations. While our technical personnel will be happy to respond to questions regarding safe handling and use procedures, safe handling and use remains the responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be construed as a recommendation to infringe any existing patents or violate any federal, state or local laws, rules, regulations or ordinances.
This Material Data Safety Sheet (MSDS) covers the following materials:
SODIUM SILICATE LIQUID LILICEOUS (ALL GRADES)
SODIUM SILICATE LIQUID GRADE 40
SODIUM SILICATE LIQUID GRADE 40 CLEAR
SODIUM SILICATE LIQUID TOLL
SODIUM SILICATE LIQUID GRADE 33
SODIUM SILICATE LIQUID GRADE 42 H
SODIUM SILICATE LIQUID GRADE 42
SODIUM SILICATE LIQUID 3M275
SODIUM SILICATE LIQUID PILOT SPECIAL
SODIUM SILICATE LIQUID GRADE 47
SODIUM SILICATE LIQUID GRADE 40 L
SODIUM SILICATE LIQUID 47 L
SODIUM SILICATE LIQUID GRADE CLEAR
SODIUM SILICATE LIQUID GRADE 20 CLEAR
SODIUM SILICATE LIQUID GRADE 42 S
SODIUM SILICATE LIQUID GRADE 49FG
SODIUM SILICATE LIQUID GRADE 45
SIGNAL WORD: WARNING
HAZARD WARNINGS: Irritating to eyes, skin, respiratory tract and gastrointestinal tract.
PRECAUTIONS: Avoid contact with eyes, skin and clothing. Avoid breathing dust, vapors or mist. Do not swallow. Use with adequate ventilation. Wear a NIOSH/MSHA approved respirator, chemical splash goggles, full-face shield, protective clothing and chemical resistant gloves. Wash thoroughly after handling. Avoid contact with acids. Before using, read Material Safety Data Sheet (MSDS) for this material.
FIRST AID
EYES: IMMEDIATELY flush eyes with a directed stream of water for at least a5 minutes, forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. IF IRRITATION PERSISTS GET MEDICAL ATTENTION.
SKIN: Was thoroughly with soap and water. Wash clothing before reuse. IF IRRITATION OCCURS, GET MEDICAL ATTENTION.
INHALATION: Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops, have a trained person administer artificial respiration. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. (If available, give several glasses of milk.) If vomiting occurs spontaneously, keep airway clear and give more water. GET MEDICAL ATTENTION IMMEDIATELY.
IN CASE OF SPILL OR LEAK: Contain spill with dike to prevent entry into sewers or waterways. Dry material can be shoveled up; liquid material can be removed with a vacuum truck. Neutralize remaining traces with any dilute inorganic acid (hydrochloric, sulfuric or acetic acid). Flush spill area with water followed by a liberal covering of sodium carbonate. All clean-up material should be removed for proper treatment or disposal. Spills on other than pavement (e.g. Dirt or sand) may be handled by removing the affected soil and placing in approved containers.
Spills or releases should be reported, if required, to the appropriate local, state and federal agencies.
FIRE: Non-flammable / Non-combustible.
Use extinguishing medium as appropriate for surrounding fire.
HANDLING AND STORAGE:
Keep container tightly closed and properly labeled. Do NOT store in aluminum container or use aluminum fittings or transfer lines, as flammable hydrogen gas can be generated.
DISPOSAL: Dispose of all waste and contaminated equipment in accordance with all applicable federal, state and local health and environmental regulations.
INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS:
This product contains:
CAS# 7732-18-5 Water
CAS# 1344-09-8 Silicic acid, sodium salt
HMIS RATING: Health = 2 Flammability = 0 Reactivity = 0
LABEL NUMBER: 119M35887
FOR INDUSTRIAL USE ONLY
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MANUFACTURER DISCLAIMER
This data is based on our present knowledge. However, they shall not constitute a guarantee for specific product features and shall not establish a legal valid contractual relationship.
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